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Thev3/v2+v6fermi resonance in SF6and its relevance to multiphoton excitation

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
82
Issue
2
Identifiers
DOI: 10.1016/0009-2614(81)85137-8
Disciplines
  • Physics

Abstract

Abstract Quantitative calculations of the nv 3 and ( n−1) v 3 + ( v 2 + v 6) band origins in SF 6 are presented which show that together these two sequences of vibrational states can provide a resonant pathway of dipole-coupled transitions for multiphoton absorption of about ten infrared quanta.

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