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Mechanistic alteration in micellar peptide esterolysis reactions

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
22
Issue
25
Identifiers
DOI: 10.1016/s0040-4039(01)82904-x

Abstract

Abstract Buffer or CTACl-catalyzed basic cleavages of Z - D - or L -AA- L -Pro p -nitrophenyl esters proceed mainly via intramolecular cyclization to diketopiperazines. These reactions are more facile with DL than with LL substrates.

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