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Reaction of low valent transition metal complexes and their phosphine derivatives with Karl Fischer reagent

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
66
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)93898-1

Abstract

Abstract The Karl Fischer reagent reacts with many low valent transition metal complexes to bring about oxidation of the metal. The reaction can be used for the oxidimetric determination of these complexes in solution and must be taken into account when P III ligands are determined in low valent metal complexes.

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