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2-aminothiazole and 2-aminothiazolinone derivatives.

Authors
  • Toplak, Renata
  • Lah, Nina
  • Volmajer, Julija
  • Leban, Ivan
  • Majcen Le Maréchal, Alenka
Type
Published Article
Journal
Acta crystallographica. Section C, Crystal structure communications
Publication Date
Sep 01, 2003
Volume
59
Issue
Pt 9
Identifiers
PMID: 12944658
Source
Medline
License
Unknown

Abstract

The reaction of different substituted alpha-cyanooxiranes with thiourea resulted in the formation of the 2-aminothiazolinone derivative 2-amino-5-(2,5-dimethoxyphenyl)-1,3-thiazol-4(5H)-one, C(11)H(12)N(2)O(3)S, (I), and the 2-aminothiazole derivative ethyl 2-amino-5-(2,5-dimethoxyphenyl)-1,3-thiazole-4-carboxylate, C(14)H(16)N(2)O(4)S, (II). The geometries of the two crystallographically independent molecules in (II) are nearly identical but mirror related. The crystal structures of both compounds contain two types of intermolecular hydrogen bonds.

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