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2,4-Dichloro-N-o-tolyl-benzamide.

Authors
  • Saeed, Aamer
  • Khera, Rasheed Ahmad
  • Simpson, Jim
  • Stanley, Roderick G
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jan 01, 2009
Volume
65
Issue
Pt 7
Identifiers
DOI: 10.1107/S1600536809022752
PMID: 21582906
Source
Medline
License
Unknown

Abstract

In the title compound, C(14)H(11)Cl(2)NO, the central C-C(O)-N-C amide unit makes dihedral angles of 68.71 (11) and 54.92 (12)°, respectively, with the dichloro-benzene and tolyl rings. The two aromatic rings are inclined at 16.25 (17)°. In the crystal, N-H⋯O hydrogen bonds link mol-ecules into zigzag chains propagating in [001]. C-H⋯Cl contacts link these chains and additional C-H⋯O contacts generate stacks down b. Weak C-H⋯π and C-Cl⋯π inter-actions [Cl⋯centroid distance = 3.5422 (15) Å] may also stabilize the structure.

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