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{2,2'-[Cyclo-hexane-1,2-diylbis(nitrilo-methanyl-ylidene)]diphenolato}copper(II).

Authors
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
68
Issue
Pt 9
Identifiers
DOI: 10.1107/S1600536812036458
PMID: 22969497
Source
Medline
License
Unknown

Abstract

The title compound, [Cu(C(20)H(20)N(2)O(2))], crystallizes with two independent mol-ecules in the asymmetric unit. In each mol-ecule, the Cu(II) atom occupies the tetra-dentate N(2)O(2) cavity of the salen-type Schiff base ligand, adopting a distorted square-planar geometry with r.m.s. deviations of the coordin-ating atoms of 0.0522 (2) and 0.1128 (4) Å. No hydrogen bonds or π-π stacking inter-action are observed.

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