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Reactions of methylene active compounds with peroxorhodium phosphino complexes. Formation of hydroperoxorhodium complexes

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
332
Issue
3
Identifiers
DOI: 10.1016/0022-328x(87)85101-x

Abstract

Abstract Reactions of active methylene compounds HA (malononitrile, β-diketones, cyclopentadiene) with the dioxygen adduct [Rh(dppe)O 2]BF 4 give new hydroperoxorhodium(III) complexes of the type [Rh(dppe)(A)OOH]BF 4. The complexes readily convert PPh 3 into OPPh 3, but do not oxidise ketones or olefins, which instead undergo extensive isomerization.

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