Affordable Access

Publisher Website

Reactions of methylene active compounds with peroxorhodium phosphino complexes. Formation of hydroperoxorhodium complexes

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
332
Issue
3
Identifiers
DOI: 10.1016/0022-328x(87)85101-x

Abstract

Abstract Reactions of active methylene compounds HA (malononitrile, β-diketones, cyclopentadiene) with the dioxygen adduct [Rh(dppe)O 2]BF 4 give new hydroperoxorhodium(III) complexes of the type [Rh(dppe)(A)OOH]BF 4. The complexes readily convert PPh 3 into OPPh 3, but do not oxidise ketones or olefins, which instead undergo extensive isomerization.

There are no comments yet on this publication. Be the first to share your thoughts.

Statistics

Seen <100 times
0 Comments