Affordable Access

Publisher Website

Pseudo-stir bar hollow fiber solid/liquid phase microextraction combined with anodic stripping voltammetry for determination of lead and cadmium in water samplesSolid/liquid phase microextraction with voltammetry for determination of lead and cadmium

Authors
Journal
Journal of Advanced Research
2090-1232
Publisher
Elsevier
Identifiers
DOI: 10.1016/j.jare.2013.11.003
Keywords
  • Anodic Stripping
  • Voltammetry
  • Cadmium
  • Lead
  • Hollow Fiber Solid Liquid Phase Microextraction

Abstract

Abstract A new procedure is presented for the determination of low concentrations of lead and cadmium in water samples. Ligand assisted pseudo-stir bar hollow fiber solid/liquid phase microextraction using sol–gel sorbent reinforced with carbon nanotubes was combined with differential pulse anodic stripping voltammetry for simultaneous determination of cadmium and lead in tap water, and Darongar river water samples. In the present work, differential pulse anodic stripping voltammetry (DPASV) using a hanging mercury drop electrode (HMDE) was used in order to determine the ultra trace level of lead and cadmium ions in real samples. This method is based on accumulation of lead and cadmium ions on the electrode using different ligands; Quinolin-8-ol, 5,7-diiodo quinoline-8-ol, 4,5-diphenyl-1H-imidazole-2(3H)-one and 2-{[2-(2-Hydroxy-ethylamino)-ethylamino]-methyl}-phenol as the complexing agent. The optimized conditions were obtained. The relationship between the peak current versus concentration was linear over the range of 0.05–500ngmL−1 for Cd (II) and Pb (II). The limits of detection for lead and cadmium were 0.015ngmL−1 and 0.012ngmL−1, respectively. Under the optimized conditions, the pre-concentration factors are 2440 and 3710 for Cd (II) and Pb (II) in 5mL of water sample, respectively.

There are no comments yet on this publication. Be the first to share your thoughts.