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Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ2 N′,O}dicopper(II))

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
66
Issue
10
Identifiers
DOI: 10.1107/s1600536810034860
Source
Legacy
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

The dimeric title compound, [Cu2(C9H10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter­molecular C—H⋯N hydrogen bonds link the dimers into chains along the c axis.

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