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Evaluation of mathematical procedures for the calculation of dead-time

Authors
Journal
Journal of Chromatography A
0021-9673
Publisher
Elsevier
Publication Date
Volume
147
Identifiers
DOI: 10.1016/s0021-9673(00)85118-3
Disciplines
  • Mathematics

Abstract

Abstract An extensive study has been made of three methods of determining dead-times mathematically from retention data of n-alkanes. It has been shown that the linearization procedure suggested by Grobler and Bálisz is sufficiently accurate for online data acquisition and that four alkanes are adequate to calculate accurately the dead-time provided that the retention times are not excessive.

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