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Directed ortho metalation of silyloxybenzamides. Anion induced 0 → C silicon rearrangement

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
24
Issue
42
Identifiers
DOI: 10.1016/s0040-4039(00)85942-0

Abstract

Abstract Trialkylsilyloxybenzamines o- and m -OSiR 3 undergo directed ortho metalation-mediated silicon rearrangement to salicylamides , 6- and 3-OH by intra- and inter-molecular mechanisms respectively.

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