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Role of pre-organization around the azaphosphatrane catalyst's active site in the conversion of CO2to cyclic carbonates

Authors
Journal
Catalysis Communications
1566-7367
Publisher
Elsevier
Publication Date
Volume
52
Identifiers
DOI: 10.1016/j.catcom.2014.04.004
Keywords
  • Azaphosphatranes
  • Cyclic Carbonates
  • Co2Chemical Valorization
  • Homogeneous Catalysis
  • Epoxides

Abstract

Abstract Various N-substituted azaphosphatranes have been prepared and successfully applied to the synthesis of styrene carbonates from CO2 and epoxides. Enhancement of the catalytic properties of the azaphosphatrane was achieved upon pre-organization of the active site through hydrogen-bonding.

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