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Thermodynamics of binary mixtures containing cyclic ethers:Part III. Excess enthalpies of oxolane and 1,4-dioxane with chloroethanes and chloroethenes

Authors
Journal
Fluid Phase Equilibria
0378-3812
Publisher
Elsevier
Publication Date
Volume
71
Identifiers
DOI: 10.1016/0378-3812(92)85011-v

Abstract

Abstract Surendranath, K.N., Krishnaiah, A. and Ramakrishna, M., 1992. Thermodynamics of binary mixtures containing cyclic ethers. Part III. Excess enthalpies of oxolane and 1,4-dioxane with chloroethanes and chloroethenes. Fluid Phase Equilibria, 71: 169-176. Molar excess enthalpies, H E , at 298.15 K and atmospheric pressure are reported for ten binary liquid mixtures containing oxolane (tetrahydrofuran) and 1,4-dioxane as common components and 1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2,2-tetrachloroethane, trichloroethene and tetrachloroethene as non-common components. All the systems are characterized by exothermic mixing over the entire composition range except for the mixtures of 1,4-dioxane with tetrachloroethene, for which H E is positive. The H E data are interpreted on the basis of possible intermolecular interactions between unlike molecules.

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