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SmI2-mediated reductive enolization of α-hetero-substituted ketones and enantioselective protonation

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
38
Issue
15
Identifiers
DOI: 10.1016/s0040-4039(97)00435-8

Abstract

Abstract High enantioselectivity (up to 94% ee) has been achieved in the protonation of samarium enolates which were generated by SmI 2-mediated reduction of 2-aryl-2-methoxycyclohexanones using a C 2-symmetric chiral diol as a proton source.

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