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Selective favorskii rearrangement in macrocyclic rings

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
22
Issue
18
Identifiers
DOI: 10.1016/s0040-4039(01)90425-3

Abstract

Abstract A mixture of 2,2-dibromo-12-chlorocyclododecanone (IIa) and 2,12-dibromo-2-chlorocyclododecanone (IIb) by Favorskii rearrangement gave selectively methyl 2-chloro-1-cycloundecene-1-carboxylate (IIIa).

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