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Acyloin rearrangement of α-hydroxy acetals: Application to the methyll-mycaroside synthesis

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
35
Issue
28
Identifiers
DOI: 10.1016/s0040-4039(00)73311-9

Abstract

Acid-treatment of α-hydroxy acetals 1 induced 1,2-migration to afford α-alkoxy-β,γ-enones 2. One of the migration products was utilized for the synthesis of methyl l-mycaroside 3.

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