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μ-Oxido-bis­[bis­(phenanthroline-κ2 N,N′)(sulfato-κO)iron(III)] octa­hydrate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
67
Issue
11
Identifiers
DOI: 10.1107/s1600536811042723
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

The title complex, [Fe2O(SO4)2(C12H8N2)4]·8H2O, contains two unique FeIII cations, one oxide anion, four 1,10-phenanthroline (phen) ligands, two coordinated sulfate anions and eight lattice water mol­ecules. Each FeIII ion has an approximate octa­hedral geometry, coordinated by four N atoms from two phen mol­ecules, two O atoms from oxide and sulfate anions, respectively. The parallel phen mol­ecules form two-dimensional supermolecules through π–π stacking inter­actions [centroid–centroid distances = 3.684 (3), 3.711 (3), 3.790 (3), 3.847 (3), 3.746 (3), 3.732 (3) and 3.729 (3) Å]. This architecture is further stabilized by O—H⋯O hydrogen bonds involving the lattice water mol­ecules and sulfate O atoms.

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