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Synthesis of (±)-7-episordidin

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
43
Issue
5
Identifiers
DOI: 10.1016/s0040-4039(01)02261-4

Abstract

Abstract The stereoselective synthesis of (±)-7-episordidin, an aggregation pheromone from the male banana weevil, Cosmopolites sordidus Germar, is reported. The key step of this work is a regioselective rhodium(II)-catalyzed diazocarbonyl CH insertion reaction that simultaneously generates three of the natural product's four stereocenters. The work reported herein also represents a formal synthesis of sordidin.

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