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Synthesis of selected aminodeoxy analogs of globotriosylceramide

Authors
Journal
Carbohydrate Research
0008-6215
Publisher
Elsevier
Publication Date
Volume
322
Identifiers
DOI: 10.1016/s0008-6215(99)00231-1
Keywords
  • Globotriosylceramide Aminodeoxy Analogs

Abstract

Abstract Four aminodeoxy analogs of globotriosylceramide (6″-, 4″-, 2″-, and 6′-aminodeoxy) were synthesized by glycosylation of 3- O-benzoylated azidosphingosine with the corresponding aminodeoxy-globotriose trichloroacetimidate, followed by reduction of the azido group, N-acylation with 1-adamantaneacetic acid, and removal of the protecting groups.

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