Affordable Access

First measurements of the HCFC-142b trend from atmospheric chemistry experiment (ACE) solar occultation spectra

Authors
Publication Date
Keywords
  • Remote Sensing
  • Atmospheric Chemistry
  • Composition
  • Hydrochlorofluorocarbons
  • Trends
  • Ozone Depletion
  • Physical
  • Chemical
  • Mathematical & Earth Sciences :: Earth Sciences & Physical Geography [G02]
  • Physique
  • Chimie
  • Mathématiques & Sciences De La Terre :: Sciences De La Terre & Géographie Physique [G02]
Disciplines
  • Chemistry

Abstract

The first measurement of the HCFC-142b (CH3CClF2) trend near the tropopause has been derived from volume mixing ratio (VMR) measurements at northern and southern hemisphere mid-latitudes for the 2004-2008 time period from spaceborne solar occultation observations recorded at 0.02 cm(-1) resolution with the ACE (atmospheric chemistry experiment) Fourier transform spectrometer. The HCFC-142b molecule is currently the third most abundant HCFC (hydrochlorofluorocarbon) in the atmosphere and ACE measurements over this time span show a continuous rise in its volume mixing ratio. Monthly average measurements at northern and southern hemisphere mid-latitudes have similar increase rates that are consistent with surface trend measurements for a similar time span. A mean northern hemisphere profile for the time span shows a near constant VMR at 8-20 km altitude range, consistent on average for the same time span with in situ results. The nearly constant vertical VMR profile also agrees with model predictions of a long lifetime in the lower atmosphere. (c) 2009 Elsevier Ltd. All rights reserved.

There are no comments yet on this publication. Be the first to share your thoughts.