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An efficient synthesis of [1,1]ferrocenophane via 1,1′-bis(6-fulvenyl)ferrocene

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
205
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)82445-6

Abstract

Abstract [1,1]Ferrocenophane can be prepared by reduction of 1,1′-bis(6-fulvenyl)ferrocene with complex borohydrides to give the dianion of 1,1′-bis(cyclopentadienylmethyl)ferrocene. Reaction of this dianion with ferrous chloride produces the ferrocenophane in good yield.

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