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Reactions of a chelated alkylpalladium compound

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
240
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)93984-6
Disciplines
  • Chemistry

Abstract

Abstract The chemistry of the compound [P d(CH 2CHRCH 2N Me 2)Cl] 2 (V. R.  CH(CO 2Et) 2) with nucleophilic (PPh 3, pyridine, CO) and electrophilic (H 2, HCl) reagents is studied. Although the nucleophiles cleave the chloride bridges, they do not readily disrupt the PdN bond, and both V and its adduct are very stable with respect to decomposition via olefin elimination. As expected, however, H 2 and HCl cleave the PdC bond to give CH 3CHRCH 2NMe 2 and either Pd metal or a palladium chloride complex, respectively.

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