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Some cyclic derivatives of ethylenediamine containing silicon, boron, phosphorus, arsenic and sulphur

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
3
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)87506-3
Disciplines
  • Physics

Abstract

Abstract Interaction of 1,2-bis(alkylamino)ethanes with certain aminosilanes has given compounds containing the five-membered ring system 1,3-diaza-2-silacyclopentane. The reaction of 1,3-diethyl-2,2-dimethyl-1,3-diaza-2-silacyclopentane with phenylphosphorus dichloride, phenylboron dichloride, thionyl chloride and arsenic trichloride has given similar heterocycles containing phosphorus, boron, sulphur and arsenic at the 2-position. The infrared and NMR spectra of the compounds obtained have been recorded and discussed.

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