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Methods of calculating composition distribution in products of polymer analogue reactions

Authors
Journal
Polymer Science U S S R
0032-3950
Publisher
Elsevier
Publication Date
Volume
16
Issue
2
Identifiers
DOI: 10.1016/0032-3950(74)90578-4
Disciplines
  • Mathematics

Abstract

Abstract To describe composition heterogeneity of products of polymer analogue reactions a method is proposed for the Monte Carlo mathematical modelling and an approximate analytical method of calculation, the “modified” single Markoff approximation recommended, of which the range of applications is determined by comparing results with results of mathematical examination. Optimum mathematical conditions were found by comparing calculated distribution parameters of units with actual values. Calculations enable us to evaluate quantitatively the relation between composition heterogeneity of products of polymer analogue reactions and the effect of adjacent reacted groups.

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