Affordable Access

Publisher Website

Far infrared matrix spectra of iron chlorides Fe2Cl6, FeCl3, Fe2Cl4, and FeCl2

Authors
Journal
Journal of Molecular Spectroscopy
0022-2852
Publisher
Elsevier
Publication Date
Volume
35
Issue
2
Identifiers
DOI: 10.1016/0022-2852(70)90203-1
Disciplines
  • Physics

Abstract

Abstract The far infrared vibration spectra of Fe 2Cl 6, FeCl 3, Fe 2Cl 4, and FeCl 2 in several matrices have been studied by effusion technique using a modified Knudsen cell with two stages. IR vibrational spectra have been obtained in argon matrices whereas only parts of the spectra were obtained in nitrogen and cyclohexane matrices. Assignments for the vibrational spectra for all molecules are given, based in part on normal coordinate analysis and observed isotopic splittings. Thermodynamic functions of the natural isotopic mixtures of Fe 2Cl 6, FeCl 3, and FeCl 2 in the ideal gaseous state are presented.

There are no comments yet on this publication. Be the first to share your thoughts.