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o-Phosphinophenole durch 1,3-carbanionische umlagerungeno-metallierter aroxyphosphine

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
310
Issue
2
Identifiers
DOI: 10.1016/s0022-328x(00)99558-5

Abstract

Abstract Phosphinous acid o-bromoaryl esters or phosphorus acid o-haloaryl ester diamides react with sodium under mild conditions to give the corresponding sodium aryls which undergo rapid 1,3-carbanionic rearrangements to give o-phosphinophenolates. These may be worked up to the free phenoles or silylated by treatment with Me 3SiCl.

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