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High-resolution two-pulse spectroscopy of anthracene in solution

Authors
Journal
Journal of Luminescence
0022-2313
Publisher
Elsevier
Publication Date
Volume
81
Issue
2
Identifiers
DOI: 10.1016/s0022-2313(98)00152-5
Keywords
  • Inhomogeneous Broadening
  • Fluorescence
  • Anthracene

Abstract

Abstract Anthracene in solution was studied by a two-pulse IR/UV spectroscopic technique using frequency variable ps laser pulses in the UV. A well-structured fluorescence excitation spectrum was measured in solution and Franck Condon transitions were assigned. Assignment was simplified by the high symmetry of the anthracene structure. We observed lines with a width of well below 100 cm −1. This value is in our view the upper limit to the electronic homogeneous width of anthracene in solution.

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