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Spectroscopic evidence for carbon-carbon bonding in “carbidic” layers on metals

Authors
Journal
Surface Science
0039-6028
Publisher
Elsevier
Publication Date
Volume
248
Identifiers
DOI: 10.1016/0039-6028(91)90065-z
Disciplines
  • Physics

Abstract

Abstract We examine previously reported ultraviolet photoelectron, C K electron energy loss, and CKVV Auger spectroscopic data from “carbidic” layers formed at temperatures between 500 and 650 K on Ni(100) and Ni(111). The “carbidic” layers studied were made from either CO or C 2H 4 exposure to the metal surface. These data indicate that significant amounts of carbon-carbon bonding exists on the surface in addition to the carbon-metal bonding with the substrate, revealing the presence of chemisorbed species, such as C 2, and maybe even C 3, etc. Quantitative interpretations of the Auger data indicate that 20 to 30% of the total electron density has carbon-carbon bonding character. Observed changes in the spectra obtained from different surfaces or at different coverages are accounted for by variations in the fraction of carbon-carbon bonding character.

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