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Preparation and characterization of Ce-Fe-Zr-O(x)/MgO complex oxides for selective oxidation of methane to synthesize gas

Journal of Rare Earths
Publication Date
DOI: 10.1016/s1002-0721(10)60360-2
  • Oxygen Carriers
  • Lattice Oxygen
  • H2/Co
  • Selectivity
  • Activity
  • Rare Earths


Abstract A series of Ce-Fe-Zr-O( x)/MgO ( x denotes the mass fraction of Ce-Fe-Zr-O, x=10%, 15%, 20%, 25%, 30%) complex oxide oxygen carriers for selective oxidation of methane to synthesis gas were prepared by the co-precipitation method. The catalysts were characterized by means of X-ray diffraction (XRD) and H 2-TPR. The XRD measurements showed that MgFeO 4 particles were formed and Fe 2O 3 particles well dispersed on the oxygen carriers. The reactions between methane diluted by argon (10% CH 4) and oxygen carriers were investigated. Suitable content of CeO 2/Fe 2O 3/ZrO 2 mixed oxides could promote the reaction between methane and oxygen carriers. There are mainly two kinds of oxygen of carriers: surface lattice oxygen which had higher activity but lower selectivity, and bulk lattice oxygen which had lower activity but higher selectivity. Among all the catalysts, Ce-Fe-Zr-O(20%)/MgO exhibited the best catalytic performance. The conversion of the methane was above 56%, and the selectivity of the H 2 and CO were both above 93%, the ratio of H 2/CO was stable and approached to 2 for a long time.

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