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A construction principle for stable multiply charged molecular anions in the gas phase

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
216
Identifiers
DOI: 10.1016/0009-2614(93)e1259-j
Disciplines
  • Design

Abstract

Abstract A construction principle is discussed which allows us to design stable multiply charged molecular anions in the gas phase. A sequence of anionic potassium fluorides with two to seven excess electrons is systematically constructed on the basis of this principle. At the ab initio and ionic model level of theory the stability of these systems to electron detachment and fragmentation is investigated.

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