Affordable Access

Publisher Website

Stereo- and regioselective formation of silyl enol ethers via oxidation of vinyl anions

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
29
Issue
34
Identifiers
DOI: 10.1016/s0040-4039(00)80471-2

Abstract

Abstract Oxidation of E- and Z-vinyl lithiums with silyl peroxides 5 affords silyl enol ethers 3 in good to excellent yield with retention of configuration. This methodology represents a useful new procedure for the stereo- and regioselective synthesis of ketone enolates.

There are no comments yet on this publication. Be the first to share your thoughts.