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A novel lead(II) porous metal–organic framework constructed from a flexible bifunctional macrocyclic polyamine ligand

Authors
Journal
Inorganic Chemistry Communications
1387-7003
Publisher
Elsevier
Volume
40
Identifiers
DOI: 10.1016/j.inoche.2013.11.042
Keywords
  • Porous Framework
  • Flexible Macrocyclic Ligand
  • Main Group Metal
  • Hydrothermal Reaction
Disciplines
  • Earth Science
  • Geography

Abstract

Graphical abstract A novel porous metal–organic framework [Pb2(TETA)]·6H2O (1) has been prepared by hydrothermal reaction of lead(II) with a flexible bifunctional macrocyclic ligand. The 1D PbO chains are cross-linked via the 14-membered macrocyclic rings of TETA4− ligands in two different directions to form 3D framework with highly solvent accessible volume.

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