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Bis[4-oxido-2-oxo-2,3-di­hydro­pyrimidin-1-ium-5-carboxyl­ato(1.5−)-κ2 O 4,O 5]bis­(1,10-phenanthroline-κ2 N,N′)dysprosium(III) dihydrate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
65
Issue
10
Identifiers
DOI: 10.1107/s1600536809036848
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

In the title compound, [Dy(C5H2.5N2O4)2(C12H8N2)2]·2H2O, the DyIII ion is located on a twofold rotation axis and is coordinated in a square-anti­prismatic geometry by two chelating 1,10-phenanthroline mol­ecules as well as two 4-oxido-2-oxo-2,3-di­hydro­pyrimidin-1-ium-5-carboxyl­ato(1.5−) anions. N—H⋯O and O—H⋯O hydrogen bonds help to stabilize the crystal structure. The H atom involved in an N—H⋯N hydrogen bond is disordered around a twofold rotation axis.

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