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Electrooxidative homo-coupling of arylboronic acids catalyzed by electrogenerated cationic palladium catalysts

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
49
Issue
46
Identifiers
DOI: 10.1016/j.tetlet.2008.09.022
Disciplines
  • Chemistry

Abstract

Abstract An electrochemical method for generating cationic palladium complexes was integrated into an electrooxidative homo-coupling of arylboronic acids. In the presence of a catalytic amount of TEMPO, the homo-coupling reaction proceeded efficiently under argon to afford symmetric biaryls.

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