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N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
65
Issue
11
Identifiers
DOI: 10.1107/s1600536809042883
Source
Legacy
Keywords
  • Organic Papers

Abstract

The title compound, C18H21BrN2O, crystallizes with two mol­ecules (A and B) in the asymmetric unit (Z′ = 2). The major differences between the two mol­ecules are related to the conformations adopted by their n-butyl side chains. The phenyl rings in both mol­ecules are almost perpendicular, making dihedral angles of 79.2 (3) and 80.8 (3)°. The amide units are planar (r.m.s. deviations of 0.0018 and 0.021 Å) and almost perpendicular to the phenyl rings to which they are attached [dihedral angles of 68.9 (4) and 71.1 (4)°]. In the crystal, molecules A and B each form only an intermolecular N—H⋯O hydrogen bond with an adjacent molecule of the same kind. There are no significant intermolecular interactions between molecules A and B.

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