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Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN 1]nickel(II) deca­hydrate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
68
Issue
1
Identifiers
DOI: 10.1107/s1600536811051063
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

In the title compound, [Ni(C9H6N3O2)2(H2O)4]·10H2O, the NiII ion lies on a twofold rotation axis and displays a slightly distorted octa­hedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules, two of which also lie on the twofold rotation axis. In the crystal, the complex mol­ecules and uncoordinated water mol­ecules are linked via inter­molecular O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. π–π inter­actions between the benzene rings provide additional stability of the crystal packing [centroid–centroid distance = 3.792 (2) Å].

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