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Successful application of α-haloallyllithium for a simple, convenient preparation of α-haloallylboronate ester

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
31
Issue
49
Identifiers
DOI: 10.1016/s0040-4039(00)97254-x

Abstract

Abstract The first successful application of α-haloallyllithium, LiCH(X)CH=CH 2, conveniently generated in situ from allyl halide and LDA in THF at −78 °C, for reaction with triisopmpyl borate to produce the valuable intermediate, α-haloallylboronate ester, is described.

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