In the study, we introduce an air-stable NHC-based deoxyfluorination reagent ImCl[H$_2$F$_3$], offering a promising avenue for deoxyfluorination across various substrates. Reagent efficiently fluorinates benzyl alcohols, carboxylic acids, and P(V) compounds without external fluoride sources. A mechanistic study reveals a twostep process involving b...
Water quality in rural areas of developing countries is a notable problem. In this article, drinking water quality from eleven villages in the Pavlodar and the Akmola region of Kazakhstan was analyzed. Questionnaires of village respondents and chemical components of drinking water were analyzed to identify the quality of drinking water. In each of ...
Silver nanoparticles (AgNPs) with different sizes have been extensively adopted in various commercial products, causing ecological concerns because of the inevitable release of AgNPs into the environment. Hence, understanding the interaction of different-sized AgNPs with environmental substances is important for assessing the environmental risk and...
Despite extensive research on particulate matter (PM) pollution in India’s Indo-Gangetic Plain (IGP), source apportionment remains challenging. This study investigates the effect of particulate matter (PM10)-associated water soluble inorganic ions (WSIIs) on ambient air concentration across the middle IGP from January to December 2018. Moreover, th...
Published in Journal of Enzyme Inhibition and Medicinal Chemistry
This study refers to the intricate world of Acinetobacter baumannii , a resilient pathogenic bacterium notorious for its propensity at antibiotic resistance in nosocomial infections. Expanding upon previous findings that emphasised the bifunctional enzyme PaaY, revealing unexpected γ-carbonic anhydrase (CA) activity, our research focuses on a diffe...
The aim of this study was a systematic analysis of the influence of anions (chloride and sulfate) on the electrochemical behavior of the Co-Sn system during codeposition from gluconate baths. The pH-dependent multiple equilibria in cobalt–tin baths were calculated using stability constants. The codeposition of the metals was characterized thermodyn...
The DIGIT experiment was launched at the Tournemire Underground Research Laboratory URL with the aim of determining the effects of temperature on the transfer of analogues of most mobile radionuclides (i.e., 36Cl, 129I and 79Se) in the Toarcian clay rock, the properties of which are close to host rocks being considered for future deep geological di...
A comprehensive thermodynamic and structural study of the complexation affinities of tetra (L1), penta (L2), and hexaphenylalanine (L3) linear peptides towards several inorganic anions in acetonitrile (MeCN) and N,N-dimethylformamide (DMF) was carried out. The influence of the chain length on the complexation thermodynamics and structural changes u...
Published in Frontiers in Chemical Engineering
The studies on materials for decontamination in aqueous solutions have increasingly received greater attentions. Such contaminants as heavy metals, arsenic, fluoride and phosphate are harmful to humans and aqueous species due to higher toxicity. Zirconium based adsorbents have become more attractive due to outstanding performance in decontamination...
