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Ma, Shuang-Shuang Sun, Rui Zhang, Zi-Heng Yu, Zheng-Kun Xu, Bao-Hua
The alkylation of nitroarenes with alkanols catalysed by a phosphinesulfonate chelated ruthenium complex [Ru-1] was developed. It exhibits very different reactivity and chemoselectivity depending on acidic-basic conditions. Under either neutral or acidic conditions, nitroarenes were converted to secondary and tertiary anilines, respectively, with s...
Ma, Shuang-Shuang Sun, Rui Zhang, Zi-Heng Yu, Zheng-Kun Xu, Bao-Hua
The alkylation of nitroarenes with alkanols catalysed by a phosphinesulfonate chelated ruthenium complex [Ru-1] was developed. It exhibits very different reactivity and chemoselectivity depending on acidic-basic conditions. Under either neutral or acidic conditions, nitroarenes were converted to secondary and tertiary anilines, respectively, with s...
