The performance of solar cells based on molecular electronic materials is limited by relatively low open-circuit voltage (Voc) relative to the absorption threshold. These voltage losses must be reduced to achieve competitive power-conversion efficiencies. Voltage losses are assigned to the molecular heterojunction required to dissociate photogenera...
The authors report the development of a desirable aqueous process for ecofriendly fabrication of efficient and stable organic field-effect transistors (eco-OFETs) and polymer solar cells (eco-PSCs). Intriguingly, the addition of a typical antisolvent, water, to ethanol is found to remarkably enhance the solubility of oligoethylene glycol (OEG) side...
Here, we systematically study the effect of fluorination on the performance of all-polymer solar cells by employing a naphthalene diimide (NDI)-based polymer acceptor with thiophene-flanked phenyl co-monomer. Fluorination of the phenyl co-monomer with either two or four fluorine units is used to create a series of acceptor polymers with either no f...
Perovskite solar cells (PSCs) have reached their highest efficiency with 2,2',7,7'-tetrakis(N,N'-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). However, this material can cause problems with respect to reproducibility and stability. Herein, a solution-processable inorganic-organic double layer based on tungsten oxide (WO3) and spiro-...
Non-fullerene acceptors (NFAs) have recently outperformed their fullerene counterparts in binary bulk-heterojunction (BHJ) organic solar cells (OSCs). Further development of NFA OSCs may benefit other novel OSC device structures that alter or extend the standard BHJ concept. Here, we report such a new processing route that forms a BHJ-like morpholo...
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Controlling polymer chain alignment through processing is a means of tuning the charge transport of solution-based conjugated polymers. In this work, a processing strategy is proposed in which an external electric field (E-field) is applied to the coating blade (E-blade) to align polymer chain durin...
10.1103/PhysRevX.8.021034 / PHYSICAL REVIEW X / 8 / 2
The synthesis and characterization of copper (I) selenocyanate (CuSeCN) and its application as a solution-processable hole-transport layer (HTL) material in transistors, organic light-emitting diodes, and solar cells are reported. Density-functional theory calculations combined with X-ray photoelectron spectroscopy are used to elucidate the electro...
In this study, hybrid BHJ - bulk heterojunction polymer solar cells were fabricated by incorporating CdS quantum dots (QDs) in a blend of P3HT (donor) and PCBM (acceptor) using dichlorobenzene and chlorobenzene as solvents. CdS QDs at various ratios were mixed in a fixed amount of the P3HT and PCBM blend. The prepared samples have been characterize...
In this study, hybrid BHJ - bulk heterojunction polymer solar cells were fabricated by incorporating CdS quantum dots (QDs) in a blend of P3HT (donor) and PCBM (acceptor) using dichlorobenzene and chlorobenzene as solvents. CdS QDs at various ratios were mixed in a fixed amount of the P3HT and PCBM blend. The prepared samples have been characterize...
