Dong, Jing-Yan Wang, Hao-Nan Xie, Yan-Qian Zhang, Cheng-Pan
Published in
iScience
A copper-mediated trifluoromethyltelluration of arylboronic acids with [Me4N][TeCF3] using air as an environmental friendly oxidant is presented. The reaction proceeded smoothly under mild conditions in the presence of Cu(OTf)2 and bipyridine to provide the corresponding trifluoromethyltellurated products in good yields. Vinylboronic acid and arylb...
Safapoor, Sajedeh Dekamin, Mohammad G. Akbari, Arezoo Naimi-Jamal, M. Reza
Published in
Scientific Reports
ZnO nanoparticles embedded in a magnetic isocyanurate-based periodic mesoporous organosilica ([email protected]–ICS–ZnO) were prepared through a modified environmentally-benign procedure for the first time and properly characterized by appropriate spectroscopic and analytical methods or techniques used for mesoporous materials. The new thermally stable Fe3...
Sekhar, Adiki Raja Chitose, Youhei Janoš, Jiří Dangoor, Sahar Israeli Ramundo, Andrea Satchi-Fainaro, Ronit Slavíček, Petr Klán, Petr Weinstain, Roy
Published in
Nature Communications
Photoremovable protecting groups (PPGs) represent one of the main contemporary implementations of photochemistry. Here, the authors show that meso-methylporphyrin unites traditionally exclusive features of organic and metal-complex PPGs within a single entity.
Zhu, Haofu Zhou, Pan-Pan Wang, Yao
Published in
Nature Communications
The activation of aziridines is typically achieved via reaction with strong Lewis acids or transition metals. Here, the authors report that cooperative Se ∙ ∙∙O and Se ∙ ∙∙N noncovalent interactions can activate sulfonyl-protected aziridines, which enables their use in cycloaddition reactions with nonactivated alkenes.
Mallick, Suman Zhou, Yuli Chen, Xiaoli Tan, Ying Ning Meng, Miao Cao, Lijiu Qin, Yi He, Zi Cong Cheng, Tao Zhu, Guang Yuan
...
Published in
iScience
Characterization of covalency of intermolecular interactions in the van der Waals distance limit remains challenging because the interactions between molecules are weak, dynamic, and not measurable. Herein, we approach this issue in a series of supramolecular mixed-valence (MV) donor(D)-bridge(B)-acceptor(A) systems consisting of two bridged Mo2 un...
Cuquejo-Cid, Alberto García-Fernández, Alberto Popescu, Catalin Bermúdez-García, Juan Manuel Señarís-Rodríguez, María A Castro-García, Socorro Vázquez-García, Digna Sánchez-Andújar, Manuel
Published in
iScience
A detailed study of lead halide-layered perovskites with general formula A2PbX4 (where A is cyclohexylammonium (CHA) or cyclopentylammonium (CPA) cation and X is Cl- or Br- anion) is presented. Using variable temperature synchrotron X-ray powder diffraction, we observe that these compounds exhibit diverse crystal structures above room temperature. ...
Ryczkowska, Małgorzata Maciejewska, Natalia Olszewski, Mateusz Witkowska, Milena Makowiec, Sławomir
Published in
Scientific reports
Colorectal cancer (CRC) is the most commonly diagnosed cancer in Europe and the United States and the second leading cause of cancer related mortality. A therapeutic strategy used for the treatment of CRC involves targeting the intracellular levels of reactive oxygen species (ROS). In this study, we synthesized a series of novel tetrahydroquinolino...
Escárcega-Bobadilla, Martha V. Maldonado-Domínguez, Mauricio Romero-Ávila, Margarita Zelada-Guillén, Gustavo A.
Published in
iScience
Chemistry; Organic chemistry
Wang, Xing Li, Ling-Jun Wang, Zhen-Yu Xu, Hui Dai, Hui-Xiong
Published in
iScience
Chemistry; Organic chemistry; Organic synthesis
Radhoff, Niklas Studer, Armido
Published in
Nature Communications
The α-arylation of amides via aryl migration has attracted considerable interest in recent years. Here, the authors report a method for the preparation of bulky α-quaternary amides via a polar-radical crossover enolate oxidation-aryl migration cascade.