Electrospray ionization mass spectrometry for the hydrolysis complexes of cisplatin : implications for the hydrolysis pr...
We report herein a large study of the inhibition of tumor necrosis factor-α with 51 iridium(III) complexes, thus highlighting the influence of the nature of the ligands around the metal, their synergic effect and the role of the light.
A series of palladium complexes of the abnormal N-heterocyclic carbene ligands of the type (a-NHC)-PdI2(L) [L = NC5H5 (1-3)b and PPh3 (1-3)c] effectively catalyzed the Hiyama coupling of aryl bromides and iodides with PhSi(OMe)(3) under the highly desired fluoride-free conditions. Interestingly enough, the pyridine based trans-(1-3)b complexes and ...
A series of palladium complexes of the abnormal N-heterocyclic carbene ligands of the type (a-NHC)-PdI2(L) [L = NC5H5 (1-3)b and PPh3 (1-3)c] effectively catalyzed the Hiyama coupling of aryl bromides and iodides with PhSi(OMe)(3) under the highly desired fluoride-free conditions. Interestingly enough, the pyridine based trans-(1-3)b complexes and ...
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The synthesis of 4-(4H-chalcogenopyran-4-ylidene and 4H-chalcogenochromen-4-ylidene)-1-(phenylthio)but-2-enyl-idene complexes is described and their non-linear optical (NLO) properties have been investigated (as mu beta by EFISH). NMR studies and X-ray crystallographic analyses show that the (phenylthio)carbene fragment has a better electron-withdr...