Experimental data supporting "Understanding Electrolyte Ion Size Effects on the Performance of Conducting MOF Supercapacitors". This data set contains five folders: - Elemental Analysis Data (contains elemental analysis data from samples; .pdf, .xlsx, .txt). - XRD Data (contains laboratory XRD data from samples; .txt, .xlsx). - Gas Sorption Data (c...
Les polyoxométallates (POMs) sont des clusters anioniques d'oxydes métalliques possédant une grande richesse structurale et chimique et présentant des propriétés multiples en catalyse, biologie ou encore en optique. L'association de POMs à d'autres entités chimiques peut conduire à des matériaux composites dotés de fonctionnalités nouvelles induite...
Supercapacitors are high-power energy storage devices that will play an important role in the transition to a low-carbon society. In recent years, layered electrically conductive metal-organic frameworks (MOFs) have emerged as one of the most promising electrode materials for next-generation supercapacitors. Their crystalline and tuneable structure...
The intensifying global opioid crisis, majorly attributed to fentanyl (FT) and its analogs, has necessitated the development of rapid and ultrasensitive remote/on-site FT sensing modalities. However, current approaches for tracking FT exposure through wastewater-based epidemiology (WBE) are unadaptable, time-consuming, and require trained professio...
Interactions among biomacromolecules, predominantly noncovalent, underpin biological processes. However, recent advancements in biospecific chemistry have enabled the creation of specific covalent bonds between biomolecules, both in vitro and in vivo. This Review traces the evolution of biospecific chemistry in proteins, emphasizing the role of gen...
MIL-53(Al) is a metal-organic framework (MOF) with unique properties, including structural flexibility, thermal stability, and luminescence. Its ability to adsorb volatile organic compounds (VOCs) and water vapor makes it a promising platform for sensing applications. This study investigated the adsorption mechanism of MIL-53(Al) with different VOC...
A method for the synthesis of benzoic acids from aryl iodides using two of the most abundant and sustainable feedstocks, carbon dioxide (CO2) and water, is disclosed. Central to this method is an effective and selective electrochemical reduction of CO2 (eCO2RR) to CO, which mitigates unwanted dehalogenation reactions occurring when H2 is produced v...
Porous materials, such as porous carbons (PCs), metal-organic frameworks (MOFs), and covalent organic frameworks (COFs), show considerable potential across various fields because of their rich microporous and mesoporous structures and large surface areas, yet they grapple with challenges like environmentally unfriendly fabrication methods and poor ...
In coordination chemistry, sterically encumbering ligands are often used to control the coordination number, geometry, and electronic structure of transition-metal complexes. The m-terphenyl ligand scaffold is particularly effective in isolating reactive, low-coordinate metal complexes due to its sterically encumbering nature. In past years, we hav...
Carbon dioxide (CO2) is present in our atmosphere as the fourth most abundant gas. The non-toxicity and non-flammability of CO2 makes it an attractive C1-synthon in organic synthesis. This thesis aims to develop catalytic transformations to utilize CO2 in the preparation of organic compounds, namely carboxylic acids and cyclic carbonates. The devel...
