SINGH, C PRAKASHAM, AP GANGWAR, MK BUTCHER, RJ GHOSH, P

A series of palladium complexes supported over acyclic diaminocarbene (ADC) ligands were conveniently obtained by the hydroamination of a metal bound isonitrile moiety. In particular, the hydroamination reaction using various secondary amines namely, pyrrolidine, morpholine and piperidene on a palladium isonitrile derivative, cis-[(2,6-i-Pr2C6H3)NC...

KUMAR, D PRAKASHAM, AP DAS, S DATTA, A GHOSH, P

A series of ruthenium complexes, namely, [{1-(N-R-1-2-acetamido)-3-(R-2)-benzimidazol-2-ylidine} Ru(p-cymene)-Cl]Cl, where {R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = i-Pr (1c); R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = Et (2c); R-1 = 2,4,6-(CH3)(3)C6H2, R-2 = Et (3c)}, of benzimidazole-derived N/O-functionalized N-heterocyclic carbene ligands successfully carried out th...

KUMAR, D PRAKASHAM, AP DAS, S DATTA, A GHOSH, P

A series of ruthenium complexes, namely, [{1-(N-R-1-2-acetamido)-3-(R-2)-benzimidazol-2-ylidine} Ru(p-cymene)-Cl]Cl, where {R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = i-Pr (1c); R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = Et (2c); R-1 = 2,4,6-(CH3)(3)C6H2, R-2 = Et (3c)}, of benzimidazole-derived N/O-functionalized N-heterocyclic carbene ligands successfully carried out th...

SINGH, C PRAKASHAM, AP GANGWAR, MK BUTCHER, RJ GHOSH, P

A series of palladium complexes supported over acyclic diaminocarbene (ADC) ligands were conveniently obtained by the hydroamination of a metal bound isonitrile moiety. In particular, the hydroamination reaction using various secondary amines namely, pyrrolidine, morpholine and piperidene on a palladium isonitrile derivative, cis-[(2,6-i-Pr2C6H3)NC...

KUMAR, D PRAKASHAM, AP DAS, S DATTA, A GHOSH, P

A series of ruthenium complexes, namely, [{1-(N-R-1-2-acetamido)-3-(R-2)-benzimidazol-2-ylidine} Ru(p-cymene)-Cl]Cl, where {R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = i-Pr (1c); R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = Et (2c); R-1 = 2,4,6-(CH3)(3)C6H2, R-2 = Et (3c)}, of benzimidazole-derived N/O-functionalized N-heterocyclic carbene ligands successfully carried out th...

KUMAR, D PRAKASHAM, AP DAS, S DATTA, A GHOSH, P

A series of ruthenium complexes, namely, [{1-(N-R-1-2-acetamido)-3-(R-2)-benzimidazol-2-ylidine} Ru(p-cymene)-Cl]Cl, where {R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = i-Pr (1c); R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = Et (2c); R-1 = 2,4,6-(CH3)(3)C6H2, R-2 = Et (3c)}, of benzimidazole-derived N/O-functionalized N-heterocyclic carbene ligands successfully carried out th...

SINGH, C PRAKASHAM, AP GANGWAR, MK GHOSH, P

A binuclear fused 5-membered palladacycle (2) and a palladium complex of amido-functionalized N-heterocyclic carbene (6) successfully performed the C-sp2-C-sp type Hiyama coupling followed by cyclization giving the biologically important benzofuran compounds in a convenient time economic method involving one-pot tandem reaction between 2-iodophenol...

SINGH, C PRAKASHAM, AP GANGWAR, MK BUTCHER, RJ GHOSH, P

A series of palladium complexes supported over acyclic diaminocarbene (ADC) ligands were conveniently obtained by the hydroamination of a metal bound isonitrile moiety. In particular, the hydroamination reaction using various secondary amines namely, pyrrolidine, morpholine and piperidene on a palladium isonitrile derivative, cis-[(2,6-i-Pr2C6H3)NC...

SINGH, C PRAKASHAM, AP GANGWAR, MK GHOSH, P

A binuclear fused 5-membered palladacycle (2) and a palladium complex of amido-functionalized N-heterocyclic carbene (6) successfully performed the C-sp2-C-sp type Hiyama coupling followed by cyclization giving the biologically important benzofuran compounds in a convenient time economic method involving one-pot tandem reaction between 2-iodophenol...

KUMAR, D PRAKASHAM, AP DAS, S DATTA, A GHOSH, P

A series of ruthenium complexes, namely, [{1-(N-R-1-2-acetamido)-3-(R-2)-benzimidazol-2-ylidine} Ru(p-cymene)-Cl]Cl, where {R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = i-Pr (1c); R-1 = 2,6-(i-Pr)(2)C6H3, R-2 = Et (2c); R-1 = 2,4,6-(CH3)(3)C6H2, R-2 = Et (3c)}, of benzimidazole-derived N/O-functionalized N-heterocyclic carbene ligands successfully carried out th...