The efficient coupling of light absorbers with catalysts is the most critical step in the multielectron transfer process for CO2 conversion. Here a heterogenized photoconversion system consisting of noncovalent assembly is tested and proposed. Nafion (NO polymer is employed as a simple and robust platform that couples the light absorber (Ru-(bpy)(3...
Catechol-amine codeposition can improve the stability of a mussel-inspired coating layer (e.g., dopamine, tannic acid, gallic acid) but its superior performance on enzyme immobilization has not been studied yet. For the first time, a tannic acid-3-amino-propyltriethoxysilane (TA-APTES) coating was investigated for carrier activation and subsequent ...
Catechol-amine codeposition can improve the stability of a mussel-inspired coating layer (e.g., dopamine, tannic acid, gallic acid) but its superior performance on enzyme immobilization has not been studied yet. For the first time, a tannic acid-3-amino-propyltriethoxysilane (TA-APTES) coating was investigated for carrier activation and subsequent ...
Co3O4/N-doped reduced graphene oxide (N-RGO) nanocomposite with mesoporous structure was fabricated by using metal organic frameworks (MOFs) as both template and precursor growing on RGO sheets. Porous Co3O4 cubes were assembled and grown on the surface of N-RGO layers, while N was doped into RGO to form N-RGO in situ synthesis route. The effect of...
Co3O4/N-doped reduced graphene oxide (N-RGO) nanocomposite with mesoporous structure was fabricated by using metal organic frameworks (MOFs) as both template and precursor growing on RGO sheets. Porous Co3O4 cubes were assembled and grown on the surface of N-RGO layers, while N was doped into RGO to form N-RGO in situ synthesis route. The effect of...
Porous materials have played a major role in several applications such as catalysis, adsorption, gas storage, electronics and molecular separation. Henceforth, the design of porous materials has always been an essential field of research. Recently, covalent triazine frameworks (CTFs) have emerged as a versatile platform for such applications owing ...
Glycerol can be converted to valuable products such as epichlorohydrin which is an important intermediate applied in various industries. For example, dioxane derivatives, which are important pharmaceuticals, can be obtained from epichlorohydrin. In the present study, ZIF-8, ZIF-67, MIL-100, and UiO-66 were applied for the direct cyclodimerization o...
We performed constant-potential molecular dynamics simulations to analyse the double-layer structure and capacitive performance of supercapacitors composed of conductive metal-organic framework (MOF) electrodes and ionic liquids. The molecular modelling clarifies how ions transport and reside inside polarized porous MOFs, and then predicts the corr...
Modulator-mediated functionalization (MoFu) is introduced as a new and versatile platform tool to improve the separation performance of metal-organic framework (MOF)-based membranes, exemplified here by the creation of mixed-matrix membranes (MMMs) with enhanced CO2 separation efficiency. The unique structure of MOF-808 allows incorporation of CO2-...
status: published
