Development of new chemical processes with simplified reaction systems and work-up procedures is a challenging task. Although ionic liquids are a class of potential multifunctional compounds to simplify traditional chemical processes, their rational design is difficult due to complex interactions. In this work, a proof-of-concept strategy has been ...
Development of new chemical processes with simplified reaction systems and work-up procedures is a challenging task. Although ionic liquids are a class of potential multifunctional compounds to simplify traditional chemical processes, their rational design is difficult due to complex interactions. In this work, a proof-of-concept strategy has been ...
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A series of palladium complexes supported over acyclic diaminocarbene (ADC) ligands were conveniently obtained by the hydroamination of a metal bound isonitrile moiety. In particular, the hydroamination reaction using various secondary amines namely, pyrrolidine, morpholine and piperidene on a palladium isonitrile derivative, cis-[(2,6-i-Pr2C6H3)NC...
The addition reactions of N-heterocyclic carbenes (NHCs) are mostly known to occur through the carbenic centre (C2), which leads to a "normal" adduct. Herein, we report the abnormal addition of NHCDip 1 (1,3-(2,6-iPr(2)C(6)H(3))-imidazole-2-ylidene) to a conjugate acid of cyclic (alkyl)(amino)carbene 2 (CAAC(iPr)=1-iPr-3,3,5,5-Me-4-pyrrolinium trif...
A series of palladium complexes supported over acyclic diaminocarbene (ADC) ligands were conveniently obtained by the hydroamination of a metal bound isonitrile moiety. In particular, the hydroamination reaction using various secondary amines namely, pyrrolidine, morpholine and piperidene on a palladium isonitrile derivative, cis-[(2,6-i-Pr2C6H3)NC...
An unprecedented reactivity profile of biochemically relevant R-benzofuroxan (R=H, Me, Cl), with high structural diversity and molecular complexity on a selective {Ru(acac)(2)} (acac=acetylacetonate) platform, in conjugation with EtOH solvent mediation, is revealed. This led to the development of monomeric [Ru-III(acac)(2)(L-1R)] (1a-1c; L-1R=2-nit...
The new ferrocenylbis(oxazaphosphininone), [Fe{C5H4P(OC6H4)(CO) N-(C2H4Cl)}(2)] (1) was synthesized by the reaction of bis(dichlorophosphino) ferrocene with two equivalents of 2(2'-hydroxy) phenyloxazoline in the presence of triethylamine in 83% yield. The reactions of 1 with aq. H2O2 or elemental sulfur afforded bis-chalcogenides [Fe{C5H4P(E)(OC6H...
An unprecedented reactivity profile of biochemically relevant R-benzofuroxan (R=H, Me, Cl), with high structural diversity and molecular complexity on a selective {Ru(acac)(2)} (acac=acetylacetonate) platform, in conjugation with EtOH solvent mediation, is revealed. This led to the development of monomeric [Ru-III(acac)(2)(L-1R)] (1a-1c; L-1R=2-nit...
The addition reactions of N-heterocyclic carbenes (NHCs) are mostly known to occur through the carbenic centre (C2), which leads to a "normal" adduct. Herein, we report the abnormal addition of NHCDip 1 (1,3-(2,6-iPr(2)C(6)H(3))-imidazole-2-ylidene) to a conjugate acid of cyclic (alkyl)(amino)carbene 2 (CAAC(iPr)=1-iPr-3,3,5,5-Me-4-pyrrolinium trif...
