Parker, Gemma L; Van Lommel, Ruben; 109850; Roig, Nil; Alonso, Mercedes; Chaplin, Adrian B;
Spectroscopic and computational examination of a homologous series of rhodium(I) pybox carbonyl complexes has revealed a correlation between the conformation of the flanking aryl-substituted oxazoline donors and the carbonyl stretching frequency. This relationship is also observed experimentally for octahedral rhodium(III) and ruthenium(II) variant...
Henrion, Mickael; 116328; Mohr, Yorck; Janssens, Kwinten; 124871; Smolders, Simon; 105851; Bugaev, Aram L; Usoltsev, Oleg A; Quadrelli, Elsje Alessandra; Wisser, Florian M; De Vos, Dirk E; 12869; Canivet, Jerome;
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status: published
Hwang, Chiwon Lee, Yeosan Kim, Minjae Seo, Younggyu Cho, Seung Hwan
© 2022 Wiley-VCH GmbH.The development of new approaches to installing diverse carbon fragments to a nitrogen atom has attracted considerable attention in chemical science. While numerous strategies have been devised to forge C(sp3)−N bonds, one conceptually powerful and straightforward approach is to insert a transformable sp3-carbon unit onto a ni...
Xie, Yujuan; 159219; Huang, Liliang; Feng, Huihui; Qi, Yayu; Van der Eycken, Erik V; 7655; Feng, Huangdi;
Disclosed herein is an efficient strategy for the synthesis of 2,4,5-trisubstituted pyridines via CuI/NBS-catalyzed formal intermolecular [2+2+2] cycloaddition of easily available primary amines and nonactivated terminal alkynes. Moreover, this given reaction features a new mode of cycloaddition with high regio- and chemoselectivity, good atom- and...
Salameh, Nihad; Ferlin, Francesco; Valentini, Federica; Anastasiou, Ioannis; Vaccaro, Luigi; 101481;
status: published
Guilliams, Martin Bonnardel, Johnny Haest, Birthe Vanderborght, Bart Wagner, Camille Remmerie, Anneleen Bujko, Anna Martens, Liesbet Thoné, Tinne Browaeys, Robin
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Published in
Cell
The liver is the largest solid organ in the body, yet it remains incompletely characterized. Here we present a spatial proteogenomic atlas of the healthy and obese human and murine liver combining single-cell CITE-seq, single-nuclei sequencing, spatial transcriptomics, and spatial proteomics. By integrating these multi-omic datasets, we provide val...
Marcano, David E Salazar; Moussawi, Mhamad Aly; 135548; Anyushin, Alexander; Lentink, Sarah; 130451; Van Meervelt, Luc; 14577; Ivanovic-Burmazovic, Ivana; Parac-Vogt, Tatjana N; 37070;
Hybrid structures incorporating different organic and inorganic constituents are emerging as a very promising class of materials since they synergistically combine the complementary and diverse properties of the individual components. Hybrid materials based on polyoxometalate clusters (POMs) are particularly interesting due to their versatile catal...
Guilliams, Martin; Bonnardel, Johnny; Haest, Birthe; Vanderborght, Bart; Wagner, Camille; Remmerie, Anneleen; Bujko, Anna; Martens, Liesbet; Thone, Tinne; Browaeys, Robin;
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The liver is the largest solid organ in the body, yet it remains incompletely characterized. Here we present a spatial proteogenomic atlas of the healthy and obese human and murine liver combining single-cell CITE-seq, single-nuclei sequencing, spatial transcriptomics, and spatial proteomics. By integrating these multi-omic datasets, we provide val...
Da Silva Osterne, Vinicius Jose Verduijn, Joost Lossio, Claudia F. Parakhonskiy, Bogdan Pinto-Junior, Vanir R. Nascimento, Kyria S. Skirtach, Andre Van Damme, Els Cavada, Benildo S.
Cancer is a serious health problem mainly characterized by unregulated cell divisions. It is known that malign cells display cancer-specific glycans that can be recognized by lectins, proteins with capacity of specific binding to carbohydrates. One such protein is the Dioclea violacea lectin (DVL), a known antiproliferative lectin that has been app...
Liu, Yaxu Scattolin, Thomas Gobbo, Alberto Beliš, Marek Van Hecke, Kristof Nolan, Steven Cazin, Catherine
The development of robust, more efficient, general, easily accessible Pd(II)-NHC pre-catalysts remains a key issue in cross-coupling applications. A selection of well-defined, air and moisture stable [Pd(NHC)Cl(1-Bu-t-indenyl)] (NHC=IPr, IPrCl, IMes, SIMes, IPr*) pre-catalysts have been synthesized in good to excellent yields by reacting [Pd(1-Bu-t...