Plasma fractionation industry is by far the largest protein pharmaceutical provider, but there are still some plasma components in its industrial waste liquid that have not been utilized. This study aimed to develop a simple and efficient method for plasma protein recovery from Cohn fraction V supernatant (FVS), an effluent containing about 40% eth...
Plasma fractionation industry is by far the largest protein pharmaceutical provider, but there are still some plasma components in its industrial waste liquid that have not been utilized. This study aimed to develop a simple and efficient method for plasma protein recovery from Cohn fraction V supernatant (FVS), an effluent containing about 40% eth...
Reflecting their importance in immunity, the activity of chemokines is regulated on several levels, including tissue and context-specific expression and availability of their cognate receptor on target cells. Chemokine synergism, affecting both chemokine and chemokine receptor function, has emerged as an additional control mechanism. We previously ...
Cytochrome c Oxidase (CcO) is the terminal electron acceptor in aerobic respiratory chain, reducing O-2 to water. The released free energy is stored by pumping protons through the protein, maintaining the transmembrane electrochemical gradient. Protons are held transiently in a proton loading site (PLS) that binds and releases protons driven by the...
A gold(I)-catalyzed cascade transformation of N-alkynic 2-ynamides for the rapid and efficient synthesis of the indolizidine scaffold is developed. Through a sequential nucleophilic cyclization/enyne cycloisomerization/1,2-migration process, diverse pyrrolo[1,2-b]isoquinolines are obtained under mild conditions in a regiospecific and convergent man...
A novel Cd(II) supramolecular coordination framework containing mixed functionalized luminophore ligands, namely, [Cd(AS)2(phen)2]EtOH or 1 (where AS = 4-aminosalicylate, phen = 1,10-phenanthroline, EtOH = ethanol), was successfully synthesized as a solid-state luminescent sensor for the detection of amine vapors. The single-crystal X-ray diffracti...
status: published
status: published
Oxidative addition of aryl halides to Ni(0) is a ubiquitous elementary step in cross-coupling and related reactions, usually producing a square-planar Ni(II)-aryl intermediate. Here we show that a triphosphine ligand supports oxidative addition at a tris-ligated Ni(0) center to cleanly form stable five-coordinate Ni(II)-aryl compounds. Kinetic and ...
The surface of nominally diamagnetic colloidal CdSe nanoplatelets can demonstrate paramagnetic behaviour owing to the uncompensated spins of dangling bonds, as we reveal here by optical spectroscopy in high magnetic fields up to 15 T using the exciton spin as a probe of the surface magnetism. The strongly nonlinear magnetic field dependence of the ...
