光触媒による第一級アミンの新合成ルートを確立 --アンモニア水を窒素源とする直接合成法の開発--. 京都大学プレスリリース. 2020-07-10. / A completely new route was established to synthesize valuable primary amines from alkenes by using aqueous ammonia, that is, a simple photocatalytic hydroamination of alkenes using aqueous ammonia with a metal-loaded TiO2 photocatalyst. Although the photochemical hydroamin...
Published in Journal of the American Chemical Society
The methanol-to-olefins process over H-SAPO-34 is characterized by its high shape selectivity toward light olefins. The catalyst is a supramolecular system consisting of nanometer-sized inorganic cages, decorated by Brønsted acid sites, in which organic compounds, mostly methylated benzene species, are trapped. These hydrocarbon pool species are es...
Published in Journal of the American Chemical Society
The stability of metal-organic frameworks (MOFs) typically decreases with an increasing number of defects, limiting the number of defects that can be created and limiting catalytic and other applications. Herein, we use a hemilabile (Hl) linker to create up to a maximum of six defects per cluster in UiO-66. We synthesized hemilabile UiO-66 (Hl-UiO-...
Implementation of an effective focal cell adhesion represents a significant challenge because it requires to develop appropriate materials and processes together with assuring that cells would interact with it effectively. Various coatings are under development in the area of biomaterials including hydrogels and polymeric surfaces. Here, we analyse...
Understanding the properties and behavior of nonpolar liquids containing surfactant and colloidal particles is essential for applications such as electrophoretic ink displays and liquid toner printing. Charged inverse micelles, formed from aggregated surfactant molecules, and their effect on the electrophoretic motion of colloidal particles have be...
Published in Journal of colloid and interface science
The wetting behaviour is a key property of a porous medium that controls hydraulic conductivity in multiphase flow. While many porous materials, such as hydrocarbon reservoir rocks, are initially wetted by the aqueous phase, surface active components within the non-wetting phase can alter the wetting state of the solid. Close to the saturation endp...
Published in Journal of the American Chemical Society
Here we report a new supramolecular strategy for the selective separation of specific polycyclic aromatic hydrocarbons (PAHs) from mixtures. The use of a triethylene glycol-functionalized formylpyridine subcomponent allowed the construction of an FeII4L4 tetrahedron 1 that was capable of transferring between water and nitromethane layers, driven by...
Published in Journal of the American Chemical Society
Covalent macrocycles and three-dimensional cages were prepared by the self-assembly of di- or tritopic anilines and 2,6-diformylpyridine subcomponents around palladium(II) templates. The resulting 2,6-bis(imino)pyridyl-PdII motif contains a tridentate ligand, leaving a free coordination site on the PdII centers, which points inward. The binding of ...
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