Low-valent cobalt complexes in C–X coupling and related reactions
International audience
Photodegradation of benzisothiazolinone: Identification and biological activity of degradation products
International audience
Enantioselective Synthesis of Complex Fused Heterocycles through Chiral Phosphoric Acid Catalyzed Intramolecular Inverse...
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Enantioselective Total Synthesis of Cymoside through a Bioinspired Oxidative Cyclization of a Strictosidine Derivative
International audience
Effect of the driving force on nanoparticles growth and shape: an opto-electrochemical study
Most protocols developed to synthesize nanoparticles (NPs) and to control their shape are inspired from nucleation and growth theories. However, to rationalize the mechanisms of the shape-selective synthesis of NPs, experimental strategies allowing to probe in situ the growth of NPs are meant. Herein, metal Au or Ag nanoparticles (NPs) are produced...
Journal of The Electrochemical Society Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Pa...
The solvent 3-methoxytetrahydrothiophene 1, 1-dioxide (MESL) was synthesized and its cycling performances of grapshite and LiNi1/3Mn1/3Co1/3O2 (NMC) electrodes were investigated in view of the high anodic stability of MESL in the presence of lithium bis-trifluoromethanesulfonimidate (LiTFSI). Galvanostatic charge-discharge of graphite electrode was...
Architectures moléculaires complexes pour la reconnaissance de bio(macro)molécules d'intérêt thérapeutique
The recognition of biomolecules in complex biological media is a challenge associated with various therapeutic applications. The chemist can address this issue following two approaches: either he designs him-self and synthesises its molecules or he selects a commercially available or natural molecule and directly uses it for its properties. Followi...
Simulation of Solvent Extraction Flowsheets by a Global Model Combining Physicochemical and Engineering Approaches-Appli...
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Solid-state formation of CO and H2CO via the CHOCHO + H reaction
Glycolaldehyde (CHOCH 2 OH) and ethylene glycol (HOCH 2 CH 2 OH) are among many complex organic molecules (COM) detected in the interstellar medium (ISM). Astrophysical models proposed very often that the formation of these compounds would be directly linked to the hydrogenation of glyoxal (CHOCHO), a potential precursor which is not yet detected i...
Local electrochemical impedance spectroscopy: a window into heterogeneous interfaces
The ability to probe surface reactivity on a local scale has led to new insight on the comprehension of the electrochemical reactivity in relation with the microstructure of the surface. Among the different techniques developed in recent years, local electrochemical impedance spectroscopy has the advantage of using a transient approach to locally c...
