Published in Russian Journal of Inorganic Chemistry
Abstract—We review state-of-the-art progress in the field of graphene oxide, a material that has a wide range of applications due to its unique properties, for example, the dielectric properties of graphene oxide can be used in memristors, the use of different degrees of reduction allows creating multipolar electrodes of lithium-ion batteries and s...
Published in Russian Journal of Inorganic Chemistry
AbstractStructural features of 16 mononuclear monooxotantalum complexes have been considered. In eleven compounds (I–XI), the Та(V) atoms have different coordination polyhedra with CNTa from four and seven: a tetrahedron, octahedron, pentagonal bipyramid, and monocapped trigonal prism. Five TaO compounds (XII–XVI) contain pentahapto-bonded η5-С5Ме5...
Published in Russian Journal of Inorganic Chemistry
Abstract—This review examines the state of art in research aimed at the development of electronic paper (electronic ink, e-ink), namely, the general principles to design a colloidal system with desired properties, having sedimentation and aggregate stability, consisting of a dispersed phase (reverse-micellar nanoreactors based on pigments) and a di...
Published in Russian Journal of Inorganic Chemistry
AbstractThe condensation of m-aminobenzoic acid with dichloroglyoxime has resulted in a new dioxime, di-m-aminobenzoyl glyoxime (DmabaH4) (I). Based on the latter, coordination 2D polymers {[Zn(DmabaH2)(H2O)(dmf)] ⋅ dmf}n (II), {[Cd(DmabaH2)(H2O)2] ⋅ 0.5dmf ⋅ 4H2O}n (III), and {[Mn(DmabaH2)(H2O)(dmf)] ⋅ dmf}n (IV) have been sythesized. The composit...
Published in Russian Journal of Inorganic Chemistry
AbstractSome results on the mechanochemical synthesis of apatites with simultaneous substitutions of calcium by lanthanum and of phosphate by silicate are presented. The reagents of reaction mixtures are taken such that to synthesize the compounds containing equal concentrations of lanthanum and silicon. The synthesis is performed in an AGO-2 plane...
Published in Russian Journal of Inorganic Chemistry
AbstractNano-cage based materials are nowadays broadly investigated due to their potential applications as biosensors and drug delivery systems. In the current study, we evaluated the adsorption behavior of Aromasin (AMS) drug on C20 and C24 nano-cages at the PBE/6-311G** level of theory. AMS drug can be adsorbed on the C20 and C24 nano-cages gener...
Published in Russian Journal of Inorganic Chemistry
AbstractKinetic study of adsorption and removal capability towards coexistent acidic and basic dyes in the polluted waste water using poly-o-toluidine-zirconium phosphoborate nanocomposite has been done. Poly-o-toluidine-zirconium phosphoborate nanocomposite synthesized by controlled sol-gel process were characterized using X-ray diffraction, scann...
Published in Russian Journal of Inorganic Chemistry
AbstractDensities of sodium hypophosphite aqueous solution (NaH2PO2) with the molality varied from 1.019143 to 10.43887 mol kg–1 at temperature intervals of 5 K range from 283.15 to 363.15 K at 101.325 kPa were measured by a precise Anton Paar Digital vibrating-tube densimeter. From the density data, the thermal expansion coefficients, apparent vol...
Published in Russian Journal of Inorganic Chemistry
AbstractKinetics of catalytic CO oxidation on the surface of metal oxide catalysts decorated with noble metals used as gas-sensing materials for sensors has been studied. The majority of oxide materials (SnO2, Al2O3, zeolite, etc.) decorated with palladium and rhodium shows kinetic features resulting in ambiguous sensor response. Exception is CeO2/...
Published in Russian Journal of Inorganic Chemistry
AbstractThe scheme of temperature-dependent topologic transformations in water–oxyethylated nonylphenol–MgCl2 phase diagrams was proved experimentally. An immiscibility area appears in the homogeneous area; it is bounded by a looped binodal curve and expands as temperature rises. The monotectic equilibrium area appears when the binodal curve touche...
